Alternating chiral selectivity of aldol reactions under the confined space of mesoporous silica.
نویسندگان
چکیده
The chiral selectivities were altered and high diastereo- and enantio-selectivities of the products were obtained in water medium without adding acid co-catalysts when a primary-tertiary diamine catalyst was immobilized on mesoporous SBA-15 to form a recyclable catalyst for the direct asymmetric aldol reaction of cyclohexanone with p-nitrobenzaldehyde.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 96 شماره
صفحات -
تاریخ انتشار 2015